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J.J. Thomson's Model of Atom
- Atom is a neutral whole, negative electrons embedded in positive nucleus.
- Most of atom is empty.
- No static equilibrium between electron and positive charge.
- Density of atom is not uniform.
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Rutherford's Atomic Model
- Most of atom is empty.
- Neutral part is tiny and positively charged (nucleus).
- Electrons revolve about nucleus in circular orbits.
- Almost whole mass concentrated in nucleus (non-uniform density).
- Objections:
- Revolving electrons should continuously emit energy, leading to continuous spectrum (instead of line spectrum).
- Atom should collapse.
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Bohr's Atomic Model
- Electron can revolve only in orbits where angular momentum is integral multiple of $\frac{h}{2\pi}$.
- Such orbits are called allowed orbits or stationary states.
- As long as electron remains revolving in its allowed orbit, energy remains constant.
- When electron jumps between two allowed orbits, it radiates energy in form of photon: $\Delta E = E_2 - E_1 = hf$.
- Objections:
- Electronic orbits are not circular.
- Fine structure of atomic spectra could not be explained.
- Effect of nuclear motion on atomic spectra is not made clear.